| 1. Round | 22/07/2000 | Orlen Plock | - | Groclin Dyskobolia | 1:0 |  |
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| 2. Round | 29/07/2000 | Widzew Łódź | - | Orlen Plock | 3:2 | ||||
| 3. Round | 06/08/2000 | Orlen Plock | - | Górnik Zabrze | 1:0 | ||||
| 4. Round | 12/08/2000 | Pogoń Szczecin | - | Orlen Plock | 3:2 | ||||
| 6. Round | 27/08/2000 | Polonia Warszawa | - | Orlen Plock | 1:0 | ||||
| 7. Round | 09/09/2000 | Orlen Plock | - | Stomil Olsztyn | 1:2 | ||||
| 9. Round | 30/09/2000 | Orlen Plock | - | Śląsk Wrocław | 2:1 | |
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| 10. Round | 14/10/2000 | Ruch Chorzów | - | Orlen Plock | 1:1 | |
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| 13. Round | 04/11/2000 | Legia Warszawa | - | Orlen Plock | 1:1 | ||||
| 14. Round | 11/11/2000 | Orlen Plock | - | Zagłębie Lubin | 1:3 | |
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| 16. Round | 10/03/2001 | Groclin Dyskobolia | - | Orlen Plock | 1:2 | ||||
| 17. Round | 17/03/2001 | Orlen Plock | - | Widzew Łódź | 4:1 | ||||
| 18. Round | 31/03/2001 | Górnik Zabrze | - | Orlen Plock | 1:0 | ||||
| 19. Round | 07/04/2001 | Orlen Plock | - | Pogoń Szczecin | 1:4 |
Poland