| 2. Round | 05/08/2006 | KAA Gent | - | Excelsior Mouscron | 1:3 | ||||
| 5. Round | 09/09/2006 | Excelsior Mouscron | - | RSC Anderlecht | 1:1 | ||||
| 8. Round | 30/09/2006 | Germinal Beerschot | - | Excelsior Mouscron | 6:2 | ||||
| 11. Round | 04/11/2006 | FC Brussels | - | Excelsior Mouscron | 1:1 | ||||
| 13. Round | 19/11/2006 | Sporting Charleroi | - | Excelsior Mouscron | 1:0 | ||||
| 14. Round | 25/11/2006 | Excelsior Mouscron | - | KRC Genk | 2:2 |  |
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| 15. Round | 02/12/2006 | SV Zulte Waregem | - | Excelsior Mouscron | 0:0 | |
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| 16. Round | 09/12/2006 | Excelsior Mouscron | - | Lierse SK (old) | 2:2 | ||||
| 19. Round | 27/01/2007 | Excelsior Mouscron | - | KAA Gent | 0:3 | ||||
| 23. Round | 24/02/2007 | Excelsior Mouscron | - | RAEC Mons | 2:2 | ||||
| 25. Round | 10/03/2007 | Excelsior Mouscron | - | Germinal Beerschot | 1:0 | ||||
| 26. Round | 17/03/2007 | KVC Westerlo | - | Excelsior Mouscron | 1:0 | ||||
| 27. Round | 01/04/2007 | Excelsior Mouscron | - | Club Brugge KV | 2:1 | ||||
| 28. Round | 07/04/2007 | Excelsior Mouscron | - | FC Brussels | 2:2 | ||||
| 30. Round | 21/04/2007 | Excelsior Mouscron | - | Sporting Charleroi | 2:1 | ||||
| 31. Round | 29/04/2007 | KRC Genk | - | Excelsior Mouscron | 3:2 |
Belgium