| 5. Round | 01/09/2012 | Ross County FC | - | Kilmarnock FC | 0:0 | ||||
| 6. Round | 15/09/2012 | Hibernian FC | - | Kilmarnock FC | 2:1 | ||||
| 7. Round | 22/09/2012 | Kilmarnock FC | - | St. Mirren FC | 3:1 | ||||
| 8. Round | 29/09/2012 | Heart of Midlothian | - | Kilmarnock FC | 1:3 | ||||
| 9. Round | 06/10/2012 | Kilmarnock FC | - | Aberdeen FC | 1:3 | ||||
| 10. Round | 20/10/2012 | St. Johnstone FC | - | Kilmarnock FC | 2:1 |  |
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| 11. Round | 27/10/2012 | Celtic FC | - | Kilmarnock FC | 0:2 | ||||
| 12. Round | 03/11/2012 | Kilmarnock FC | - | Inverness CT | 1:2 | ||||
| 20. Round | 26/12/2012 | Kilmarnock FC | - | Heart of Midlothian | 1:0 | ||||
| 21. Round | 29/12/2012 | Motherwell FC | - | Kilmarnock FC | 2:2 | ||||
| 22. Round | 02/01/2013 | St. Mirren FC | - | Kilmarnock FC | 1:1 | ||||
| 23. Round | 19/01/2013 | Kilmarnock FC | - | Dundee United | 2:3 | ||||
| 16. Round | 27/01/2013 | Dundee FC | - | Kilmarnock FC | 0:0 | ||||
| 25. Round | 30/01/2013 | Celtic FC | - | Kilmarnock FC | 4:1 | ||||
| 29. Round | 27/02/2013 | Hibernian FC | - | Kilmarnock FC | 2:2 |
Northern Ireland