| 1. Round | 20/08/1994 | RSC Charleroi | - | KV Mechelen | 0:1 | ||||
| 2. Round | 27/08/1994 | Sint-Truidense VV | - | RSC Charleroi | 0:0 | ||||
| 4. Round | 09/09/1994 | RSC Charleroi | - | Standard Liège | 0:3 | ||||
| 5. Round | 17/09/1994 | RWD Molenbeek | - | RSC Charleroi | 1:0 | ||||
| 6. Round | 24/09/1994 | RSC Charleroi | - | KV Oostende | 1:0 |  |
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| 20. Round | 28/01/1995 | RSC Charleroi | - | RFC Liège | 4:1 | ||||
| 17. Round | 01/02/1995 | Royal Antwerp FC | - | RSC Charleroi | 0:2 | ||||
| 21. Round | 04/02/1995 | Standard Liège | - | RSC Charleroi | 2:0 | ||||
| 22. Round | 11/02/1995 | RSC Charleroi | - | RWD Molenbeek | 2:0 | ||||
| 23. Round | 19/02/1995 | KV Oostende | - | RSC Charleroi | 1:1 | ||||
| 24. Round | 25/02/1995 | RSC Charleroi | - | KAA Gent | 0:0 | ||||
| 25. Round | 05/03/1995 | Cercle Brugge | - | RSC Charleroi | 0:1 | ||||
| 27. Round | 17/03/1995 | Lommelse SK | - | RSC Charleroi | 2:0 | ||||
| 28. Round | 01/04/1995 | RSC Charleroi | - | Lierse SK (old) | 1:0 | |
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| 29. Round | 09/04/1995 | K.S.C. Eendracht Aalst | - | RSC Charleroi | 0:0 | ||||
| 30. Round | 17/04/1995 | RSC Charleroi | - | RSC Anderlecht | 2:1 | ||||
| 31. Round | 29/04/1995 | KSK Beveren | - | RSC Charleroi | 2:1 | ||||
| 32. Round | 06/05/1995 | RSC Charleroi | - | RFC Seraing (1904-1996) | 2:3 |
Belgium