| 12. Round | 21/01/2023 | Manchester City WFC [Women] | - | Aston Villa WFC [Women] | 1:1 | ||||
| 1. Round | 12/02/2023 | Brighton & Hove Albion WFC [Women] | - | Aston Villa WFC [Women] | 2:6 | ||||
| 14. Round | 05/03/2023 | Everton FC [Women] | - | Aston Villa WFC [Women] | 0:2 | ||||
| 15. Round | 12/03/2023 | West Ham United WFC [Women] | - | Aston Villa WFC [Women] | 1:2 |  |
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| 17. Round | 02/04/2023 | Aston Villa WFC [Women] | - | Chelsea FC Women [Women] | 0:3 | ||||
| 18. Round | 23/04/2023 | Tottenham Hotspur WFC [Women] | - | Aston Villa WFC [Women] | 3:3 | ||||
| 19. Round | 28/04/2023 | Aston Villa WFC [Women] | - | Manchester United WFC [Women] | 2:3 | |
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| 20. Round | 07/05/2023 | Reading WFC [Women] | - | Aston Villa WFC [Women] | 0:5 |
Scotland