| 2. Round | 22/08/2012 | Boca Juniors | - | Independiente | 3:3 | ||||
| Round of 16 | 26/09/2012 | Independiente | - | Liverpool | 2:1 |  |
|||
| Quarter-finals | 08/11/2012 | Universidad Católica | - | Independiente | 2:1 |
| 2. Round | 22/08/2012 | Boca Juniors | - | Independiente | 3:3 | ||||
| Round of 16 | 26/09/2012 | Independiente | - | Liverpool | 2:1 | |
|||
| Quarter-finals | 08/11/2012 | Universidad Católica | - | Independiente | 2:1 |
| Samuel Catalino Cáceres Arza | |
| Born: | 20.03.1989 |
| Place of birth: |
Itacurubí, 
Paraguay |
| Nationality: |
Paraguay
|
| Height: | 184 cm |
| Weight: | 82 kg |
| Position(s): | Centre Back |
| Foot: | right |