| 1. Round | 22/07/2006 | Stal Alchevsk | - | Metalist Kharkiv | 0:1 | ||||
| 2. Round | 30/07/2006 | Metalurh Donetsk | - | Stal Alchevsk | 2:1 |  |
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| 3. Round | 05/08/2006 | Stal Alchevsk | - | FK Illichivets | 0:2 | |
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| 10. Round | 15/10/2006 | Stal Alchevsk | - | Karpaty Lviv | 0:1 | |
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| 11. Round | 21/10/2006 | Dinamo Kiev | - | Stal Alchevsk | 3:1 | ||||
| 13. Round | 05/11/2006 | Metalurg Zaporizhya | - | Stal Alchevsk | 1:0 |
Ukraine