| 2. Round | 20/08/2005 | RBC Roosendaal | - | AFC Ajax | 0:2 |  |
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| 3. Round | 28/08/2005 | AFC Ajax | - | Feyenoord | 1:2 | ||||
| 4. Round | 10/09/2005 | Willem II | - | AFC Ajax | 0:2 | ||||
| 5. Round | 18/09/2005 | AZ Alkmaar | - | AFC Ajax | 4:2 | ||||
| 1. Round | 21/09/2005 | AFC Ajax | - | ADO Den Haag | 2:2 |  |
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| 6. Round | 24/09/2005 | AFC Ajax | - | Roda JC Kerkrade | 4:1 | |
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| 7. Round | 02/10/2005 | Sparta Rotterdam | - | AFC Ajax | 1:2 | |
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| 9. Round | 23/10/2005 | PSV Eindhoven | - | AFC Ajax | 1:0 | ||||
| 10. Round | 28/10/2005 | AFC Ajax | - | sc Heerenveen | 0:0 | ||||
| 14. Round | 04/12/2005 | AFC Ajax | - | RKC Waalwijk | 4:1 | ||||
| 15. Round | 11/12/2005 | Vitesse | - | AFC Ajax | 0:2 | |
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| 27. Round | 05/03/2006 | AFC Ajax | - | Sparta Rotterdam | 6:0 | ||||
| 28. Round | 11/03/2006 | AFC Ajax | - | PSV Eindhoven | 0:0 | ||||
| 29. Round | 19/03/2006 | FC Groningen | - | AFC Ajax | 3:2 | ||||
| 34. Round | 16/04/2006 | RKC Waalwijk | - | AFC Ajax | 2:4 |
South Africa
