| 6. Round | 27/02/2023 | Alianza Petrolera | - | Independiente Medellín | 0:1 | ||||
| 7. Round | 04/03/2023 | La Equidad | - | Alianza Petrolera | 1:1 |  |
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| 2. Round | 10/03/2023 | Alianza Petrolera | - | Deportivo Pasto | 3:1 | ||||
| 8. Round | 13/03/2023 | Alianza Petrolera | - | Unión Magdalena | 2:1 | ||||
| 9. Round | 19/03/2023 | América de Cali | - | Alianza Petrolera | 1:0 | ||||
| 10. Round | 25/03/2023 | Alianza Petrolera | - | Atlético Bucaramanga | 2:0 | |
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| 11. Round | 04/04/2023 | Atlético Junior | - | Alianza Petrolera | 1:0 | ||||
| 12. Round | 10/04/2023 | Alianza Petrolera | - | Santa Fe | 3:1 | ||||
| 13. Round | 15/04/2023 | Alianza Petrolera | - | Jaguares de Córdoba | 3:0 | ||||
| 14. Round | 19/04/2023 | Once Caldas | - | Alianza Petrolera | 1:2 | ||||
| 15. Round | 22/04/2023 | Alianza Petrolera | - | Deportivo Cali | 0:3 | ||||
| 16. Round | 25/04/2023 | Atlético Bucaramanga | - | Alianza Petrolera | 1:1 | ||||
| 17. Round | 30/04/2023 | Alianza Petrolera | - | Águilas Doradas | 2:1 |  |
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| 18. Round | 07/05/2023 | Deportes Tolima | - | Alianza Petrolera | 2:1 | ||||
| 3. Round | 11/05/2023 | Millonarios | - | Alianza Petrolera | 3:1 | |
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| 19. Round | 15/05/2023 | Alianza Petrolera | - | Atlético Nacional | 2:1 | |
Colombia