| 1. Round | 05/09/1965 | UD Las Palmas | - | Espanyol Barcelona | 1:1 | ||||
| 2. Round | 12/09/1965 | RCD Mallorca | - | UD Las Palmas | 4:1 | ||||
| 3. Round | 19/09/1965 | UD Las Palmas | - | Real Zaragoza | 2:1 |  |
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| 4. Round | 26/09/1965 | UD Las Palmas | - | CE Sabadell | 1:0 | |
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| 10. Round | 21/11/1965 | UD Las Palmas | - | Valencia CF | 0:2 | ||||
| 11. Round | 28/11/1965 | UD Las Palmas | - | Athletic Club | 1:1 | |
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| 12. Round | 05/12/1965 | Córdoba CF | - | UD Las Palmas | 1:1 | ||||
| 13. Round | 12/12/1965 | Real Madrid | - | UD Las Palmas | 3:1 | ||||
| 14. Round | 19/12/1965 | UD Las Palmas | - | Atlético Madrid | 1:1 | ||||
| 15. Round | 25/12/1965 | FC Barcelona | - | UD Las Palmas | 3:2 | ||||
| 16. Round | 02/01/1966 | Espanyol Barcelona | - | UD Las Palmas | 1:1 | ||||
| 17. Round | 06/01/1966 | UD Las Palmas | - | RCD Mallorca | 0:0 | ||||
| 26. Round | 06/03/1966 | Athletic Club | - | UD Las Palmas | 1:1 |
Spain