| 1. Round | 14/07/2019 | Once Caldas | - | Atlético Nacional | 1:2 |  |
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| 3. Round | 28/07/2019 | Jaguares de Córdoba | - | Atlético Nacional | 1:1 | ||||
| 4. Round | 07/08/2019 | Atlético Nacional | - | Atlético Huila | 4:1 | |
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| 5. Round | 10/08/2019 | La Equidad | - | Atlético Nacional | 0:0 | ||||
| 6. Round | 19/08/2019 | Atlético Nacional | - | Unión Magdalena | 3:1 | ||||
| 8. Round | 25/08/2019 | Atlético Nacional | - | Independiente Medellín | 5:2 | ||||
| 9. Round | 02/09/2019 | Atlético Nacional | - | Millonarios | 1:1 | ||||
| 10. Round | 08/09/2019 | Independiente Medellín | - | Atlético Nacional | 1:4 | |
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| 11. Round | 15/09/2019 | Atlético Nacional | - | Cúcuta Deportivo | 2:3 | |
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| 13. Round | 30/09/2019 | Atlético Nacional | - | Deportes Tolima | 1:0 | ||||
| 14. Round | 02/10/2019 | Alianza Petrolera | - | Atlético Nacional | 0:0 |
Colombia