| 2. Round | 02/10/2022 | Angrense | - | CD Nacional | 0:2 | ||||
| 3. Round | 15/10/2022 | CD Nacional | - | UD Oliveirense | 3:1 aet |  |
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| 4. Round | 09/11/2022 | CD Nacional | - | CD Tondela | 1:0 | ||||
| Round of 16 | 11/01/2023 | CD Nacional | - | Rabo Peixe | 1:0 | ||||
| Quarter-finals | 09/02/2023 | Casa Pia AC | - | CD Nacional | 2:5 aet | |
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| Semi-finals | 12/04/2023 | CD Nacional | - | Sporting Braga | 0:5 | ||||
| Semi-finals | 25/04/2023 | Sporting Braga | - | CD Nacional | 2:2 |
Mozambique