| 1. Round | 10/11/1999 | Villarreal CF | - | CD Leganés | 0:1 | ||||
| 1. Round | 01/12/1999 | CD Leganés | - | Villarreal CF | 0:3 aet | ||||
| Round of 16 | 19/01/2000 | SD Compostela | - | Villarreal CF | 3:0 |  |
| 1. Round | 10/11/1999 | Villarreal CF | - | CD Leganés | 0:1 | ||||
| 1. Round | 01/12/1999 | CD Leganés | - | Villarreal CF | 0:3 aet | ||||
| Round of 16 | 19/01/2000 | SD Compostela | - | Villarreal CF | 3:0 | |
| Xavier Roca Mateo | |
| Born: | 19.01.1974 |
| Place of birth: |
Barcelona, 
Spain |
| Nationality: |
Spain
|
| Height: | 177 cm |
| Weight: | 74 kg |
| Position(s): | Right Back |