| 5. Round | 14/09/2012 | Paris Saint-Germain | - | Toulouse FC | 2:0 | ||||
| 6. Round | 22/09/2012 | Toulouse FC | - | Stade Rennais | 2:2 | ||||
| 7. Round | 29/09/2012 | ESTAC Troyes | - | Toulouse FC | 0:2 | ||||
| 8. Round | 06/10/2012 | Toulouse FC | - | Valenciennes FC | 2:2 | ||||
| 9. Round | 20/10/2012 | Évian Thonon Gaillard | - | Toulouse FC | 0:4 | ||||
| 10. Round | 27/10/2012 | Toulouse FC | - | Stade Brestois 29 | 3:1 | ||||
| 11. Round | 04/11/2012 | Girondins Bordeaux | - | Toulouse FC | 1:0 | ||||
| 12. Round | 10/11/2012 | Toulouse FC | - | AC Ajaccio | 2:4 | ||||
| 13. Round | 18/11/2012 | OGC Nice | - | Toulouse FC | 1:0 | ||||
| 14. Round | 25/11/2012 | Toulouse FC | - | Olympique Lyonnais | 3:0 | ||||
| 15. Round | 02/12/2012 | FC Lorient | - | Toulouse FC | 1:0 | ||||
| 20. Round | 11/01/2013 | AS Saint-Étienne | - | Toulouse FC | 2:2 | ||||
| 22. Round | 26/01/2013 | Stade de Reims | - | Toulouse FC | 1:1 | ||||
| 23. Round | 01/02/2013 | Toulouse FC | - | Paris Saint-Germain | 0:4 | ||||
| 24. Round | 10/02/2013 | Stade Rennais | - | Toulouse FC | 2:0 | ||||
| 25. Round | 16/02/2013 | Toulouse FC | - | ESTAC Troyes | 2:2 | ||||
| 32. Round | 14/04/2013 | Olympique Lyonnais | - | Toulouse FC | 3:1 |
Guinea-Bissau
