| 6. Round | 31/08/2024 | KV Mechelen | - | Sporting Charleroi | 5:2 | ||||
| 7. Round | 15/09/2024 | Sporting Charleroi | - | K Beerschot VA | 3:0 | ||||
| 11. Round | 20/10/2024 | Standard Liège | - | Sporting Charleroi | 2:1 | ||||
| 14. Round | 09/11/2024 | Sporting Charleroi | - | KVC Westerlo | 1:0 | ||||
| 16. Round | 30/11/2024 | Sporting Charleroi | - | Standard Liège | 1:1 | ||||
| 17. Round | 08/12/2024 | Royal Antwerp FC | - | Sporting Charleroi | 1:3 | ||||
| 19. Round | 21/12/2024 | Sporting Charleroi | - | Sint-Truidense VV | 2:1 | ||||
| 22. Round | 17/01/2025 | KAA Gent | - | Sporting Charleroi | 1:1 |  |
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| 23. Round | 25/01/2025 | Sporting Charleroi | - | Cercle Brugge | 1:1 | ||||
| 24. Round | 01/02/2025 | Sporting Charleroi | - | FCV Dender EH | 5:0 | ||||
| 25. Round | 09/02/2025 | K Beerschot VA | - | Sporting Charleroi | 1:1 | ||||
| 26. Round | 16/02/2025 | Sporting Charleroi | - | RSC Anderlecht | 0:1 | ||||
| 27. Round | 22/02/2025 | KVC Westerlo | - | Sporting Charleroi | 1:3 | ||||
| 28. Round | 28/02/2025 | Sporting Charleroi | - | KRC Genk | 1:1 | ||||
| 29. Round | 08/03/2025 | Sporting Charleroi | - | KV Mechelen | 0:1 | ||||
| 30. Round | 16/03/2025 | Club Brugge KV | - | Sporting Charleroi | 4:2 |
Slovenia