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| 1st(1st leg) | SS Pennarossa | - | SS Murata | 1:1 (0:0) | ||
| 2nd (2nd leg) | SS Murata | - | SS Pennarossa | 1:2 (1:1) | ||
| 1st(1st leg): 03/05/2022 19:45 | 2nd (2nd leg): 07/05/2022 14:00 | Winner: SS Pennarossa | ||||
| 1st(1st leg) | SC Faetano | - | SS San Giovanni | 1:1 (0:1) | ||
| 2nd (2nd leg) | SS San Giovanni | - | SC Faetano | 1:2 (0:0) | ||
| 1st(1st leg): 03/05/2022 19:45 | 2nd (2nd leg): 07/05/2022 14:00 | Winner: SC Faetano | ||||
| 1st(1st leg) | AC Libertas | - | FC Domagnano | 5:0 (1:0) | ||
| 2nd (2nd leg) | FC Domagnano | - | AC Libertas | 0:3 (0:1) | ||
| 1st(1st leg): 03/05/2022 19:45 | 2nd (2nd leg): 07/05/2022 14:00 | Winner: AC Libertas | ||||
| 1st(1st leg) | SS Folgore/Falciano | - | FC Fiorentino | 0:2 (0:1) | ||
| 2nd (2nd leg) | FC Fiorentino | - | SS Folgore/Falciano | 1:2 (1:1) | ||
| 1st(1st leg): 03/05/2022 19:45 | 2nd (2nd leg): 07/05/2022 14:00 | Winner: FC Fiorentino | ||||
