| 1. Round | 14/07/2012 | ND Gorica | - | NK Maribor | 1:3 | ||||
| 2. Round | 21/07/2012 | NK Maribor | - | FC Koper | 0:0 | ||||
| 3. Round | 29/07/2012 | ND Mura 05 | - | NK Maribor | 1:3 |  |
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| 4. Round | 04/08/2012 | NK Maribor | - | NK Triglav | 1:0 | ||||
| 7. Round | 25/08/2012 | NK Celje | - | NK Maribor | 0:2 | |
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| 8. Round | 01/09/2012 | NK Maribor | - | Rudar Velenje | 4:0 | |
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| 9. Round | 15/09/2012 | NK Aluminij | - | NK Maribor | 1:5 | |
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| 10. Round | 23/09/2012 | NK Maribor | - | ND Gorica | 4:0 | |
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| 12. Round | 30/09/2012 | NK Maribor | - | ND Mura 05 | 1:0 | ||||
| 13. Round | 07/10/2012 | NK Triglav | - | NK Maribor | 1:0 | ||||
| 14. Round | 20/10/2012 | NK Maribor | - | Olimpija Ljubljana | 1:0 | ||||
| 16. Round | 03/11/2012 | NK Maribor | - | NK Celje | 1:2 | ||||
| 18. Round | 11/11/2012 | NK Maribor | - | NK Aluminij | 2:1 | |
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| 19. Round | 17/11/2012 | ND Gorica | - | NK Maribor | 1:6 |
Slovenia