| 3. Round | 07/08/2011 | Motherwell FC | - | Heart of Midlothian | 1:0 | ||||
| 5. Round | 21/08/2011 | Kilmarnock FC | - | Heart of Midlothian | 0:0 | ||||
| 6. Round | 28/08/2011 | Heart of Midlothian | - | Hibernian FC | 2:0 | ||||
| 14. Round | 05/11/2011 | St. Mirren FC | - | Heart of Midlothian | 0:0 | ||||
| 20. Round | 24/12/2011 | Heart of Midlothian | - | Motherwell FC | 2:0 | ||||
| 21. Round | 28/12/2011 | Aberdeen FC | - | Heart of Midlothian | 0:0 | ||||
| 22. Round | 02/01/2012 | Hibernian FC | - | Heart of Midlothian | 1:3 | ||||
| 25. Round | 08/02/2012 | Heart of Midlothian | - | Celtic FC | 0:4 |  |
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| 26. Round | 11/02/2012 | Kilmarnock FC | - | Heart of Midlothian | 1:1 | ||||
| 27. Round | 18/02/2012 | Motherwell FC | - | Heart of Midlothian | 3:0 | ||||
| 28. Round | 25/02/2012 | Heart of Midlothian | - | Dundee United | 0:2 | ||||
| 29. Round | 03/03/2012 | Rangers FC | - | Heart of Midlothian | 1:2 | ||||
| 30. Round | 18/03/2012 | Heart of Midlothian | - | Hibernian FC | 2:0 | ||||
| 31. Round | 24/03/2012 | St. Johnstone FC | - | Heart of Midlothian | 2:1 | ||||
| 32. Round | 31/03/2012 | Heart of Midlothian | - | Aberdeen FC | 3:0 | ||||
| 33. Round | 07/04/2012 | Dunfermline Athletic | - | Heart of Midlothian | 1:2 |
England
