| 1. Round | 12/07/2005 | FK Illichivets | - | Metalist Kharkiv | 0:2 | ||||
| 2. Round | 17/07/2005 | FK Illichivets | - | Vorskla Poltava | 3:2 |  |
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| 5. Round | 08/08/2005 | Dinamo Kiev | - | FK Illichivets | 1:1 | ||||
| 13. Round | 23/10/2005 | Arsenal Kiev | - | FK Illichivets | 0:2 | ||||
| 14. Round | 30/10/2005 | FK Illichivets | - | Stal Alchevsk | 3:0 | ||||
| 16. Round | 20/11/2005 | Metalist Kharkiv | - | FK Illichivets | 1:1 |  |
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| 19. Round | 08/12/2005 | Chernomorets Odessa | - | FK Illichivets | 1:2 |
Ukraine