| 1. Round | 14/07/2013 | Shakhtar Donetsk | - | Hoverla Uzhgorod | 2:0 | ||||
| 3. Round | 28/07/2013 | Shakhtar Donetsk | - | Chernomorets Odessa | 1:0 | ||||
| 5. Round | 10/08/2013 | Tavriya Simferopol (1958-2014) | - | Shakhtar Donetsk | 0:4 | ||||
| 7. Round | 25/08/2013 | Dnipro Dnipropetrovsk | - | Shakhtar Donetsk | 3:1 | ||||
| 10. Round | 21/09/2013 | Shakhtar Donetsk | - | Vorskla Poltava | 3:0 | ||||
| 11. Round | 28/09/2013 | Metalurh Donetsk | - | Shakhtar Donetsk | 2:2 | ||||
| 12. Round | 04/10/2013 | Shakhtar Donetsk | - | Arsenal Kiev | annull. | ||||
| 13. Round | 19/10/2013 | FK Illichivets | - | Shakhtar Donetsk | 1:3 | ||||
| 16. Round | 09/11/2013 | Hoverla Uzhgorod | - | Shakhtar Donetsk | 0:2 | ||||
| 18. Round | 03/12/2013 | Chernomorets Odessa | - | Shakhtar Donetsk | 0:1 | ||||
| 21. Round | 16/03/2014 | Metalurg Zaporizhya | - | Shakhtar Donetsk | 0:3 | ||||
| 22. Round | 22/03/2014 | Shakhtar Donetsk | - | Dnipro Dnipropetrovsk | 0:2 | ||||
| 19. Round | 16/04/2014 | Dinamo Kiev | - | Shakhtar Donetsk | 0:2 | ||||
| 26. Round | 19/04/2014 | Shakhtar Donetsk | - | Metalurh Donetsk | 2:1 | ||||
| 28. Round | 02/05/2014 | Shakhtar Donetsk | - | FK Illichivets | 3:1 | ||||
| 29. Round | 11/05/2014 | Zorya Lugansk | - | Shakhtar Donetsk | 1:3 |
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