| 2. Round | 21/07/2013 | PFK Sevastopol | - | Shakhtar Donetsk | 1:3 | ||||
| 4. Round | 04/08/2013 | Shakhtar Donetsk | - | Dinamo Kiev | 3:1 | ||||
| 6. Round | 18/08/2013 | Shakhtar Donetsk | - | Metalurg Zaporizhya | 2:0 | ||||
| 8. Round | 31/08/2013 | Shakhtar Donetsk | - | Metalist Kharkiv | 1:1 | ||||
| 9. Round | 13/09/2013 | Karpaty Lviv | - | Shakhtar Donetsk | 3:2 |  |
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| 14. Round | 26/10/2013 | Shakhtar Donetsk | - | Zorya Lugansk | 4:0 | ||||
| 15. Round | 01/11/2013 | Volyn Lutsk | - | Shakhtar Donetsk | 2:0 | ||||
| 17. Round | 23/11/2013 | Shakhtar Donetsk | - | PFK Sevastopol | 4:0 | ||||
| 23. Round | 30/03/2014 | Metalist Kharkiv | - | Shakhtar Donetsk | 2:4 | ||||
| 24. Round | 05/04/2014 | Shakhtar Donetsk | - | Karpaty Lviv | 3:0 | ||||
| 25. Round | 12/04/2014 | Vorskla Poltava | - | Shakhtar Donetsk | 1:0 | ||||
| 20. Round | 23/04/2014 | Shakhtar Donetsk | - | Tavriya Simferopol (1958-2014) | 2:1 | ||||
| 30. Round | 18/05/2014 | Shakhtar Donetsk | - | Volyn Lutsk | 2:0 |
Ukraine