| Group E | 17/09/2008 | Manchester United | - | Villarreal CF | 0:0 |  |
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| Group E | 30/09/2008 | Villarreal CF | - | Celtic FC | 1:0 | ||||
| Group E | 25/11/2008 | Villarreal CF | - | Manchester United | 0:0 | ||||
| Group E | 10/12/2008 | Celtic FC | - | Villarreal CF | 2:0 | |
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| Round of 16 | 25/02/2009 | Villarreal CF | - | Panathinaikos | 1:1 | ||||
| Round of 16 | 10/03/2009 | Panathinaikos | - | Villarreal CF | 1:2 |  |
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| Quarter-finals | 07/04/2009 | Villarreal CF | - | Arsenal FC | 1:1 | ||||
| Quarter-finals | 15/04/2009 | Arsenal FC | - | Villarreal CF | 3:0 |
Argentina
Spain