| 1. Round | 25/01/2012 | El Nacional | - | Libertad | 1:0 | ||||
| 1. Round | 31/01/2012 | Libertad | - | El Nacional | 4:1 |  |
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| Group 5 | 10/02/2012 | Libertad | - | Alianza Lima | 4:1 | ||||
| Group 5 | 15/03/2012 | Libertad | - | Vasco da Gama - RJ | 1:1 | |
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| Group 5 | 06/04/2012 | Libertad | - | Nacional | 2:1 | ||||
| Group 5 | 13/04/2012 | Alianza Lima | - | Libertad | 1:2 | |
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| Round of 16 | 02/05/2012 | Cruz Azul | - | Libertad | 1:1 | ||||
| Round of 16 | 09/05/2012 | Libertad | - | Cruz Azul | 2:0 | |
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| Quarter-finals | 16/05/2012 | Libertad | - | Universidad de Chile | 1:1 | |
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| Quarter-finals | 25/05/2012 | Universidad de Chile | - | Libertad | 5:3 pso | |
Paraguay