| 6. Round | 09/09/2006 | Vorskla Poltava | - | Shakhtar Donetsk | 0:1 | ||||
| 7. Round | 17/09/2006 | Shakhtar Donetsk | - | Tavriya Simferopol (1958-2014) | 3:0 | ||||
| 8. Round | 23/09/2006 | Dnipro Dnipropetrovsk | - | Shakhtar Donetsk | 1:1 | ||||
| 9. Round | 01/10/2006 | Shakhtar Donetsk | - | Stal Alchevsk | 3:1 | ||||
| 12. Round | 27/10/2006 | Shakhtar Donetsk | - | Karpaty Lviv | 4:1 | ||||
| 13. Round | 06/11/2006 | Dinamo Kiev | - | Shakhtar Donetsk | 1:0 | ||||
| 14. Round | 11/11/2006 | Shakhtar Donetsk | - | Chernomorets Odessa | 2:0 | ||||
| 15. Round | 18/11/2006 | Metalurg Zaporizhya | - | Shakhtar Donetsk | 0:3 | ||||
| 16. Round | 27/11/2006 | FK Krivbas (old) | - | Shakhtar Donetsk | 0:1 | ||||
| 17. Round | 03/03/2007 | Shakhtar Donetsk | - | Zorya Lugansk | 3:0 | ||||
| 18. Round | 11/03/2007 | Metalist Kharkiv | - | Shakhtar Donetsk | 0:1 | ||||
| 25. Round | 06/05/2007 | Shakhtar Donetsk | - | FK Kharkiv | 1:2 | ||||
| 27. Round | 19/05/2007 | Karpaty Lviv | - | Shakhtar Donetsk | 0:0 | ||||
| 28. Round | 23/05/2007 | Shakhtar Donetsk | - | Dinamo Kiev | 2:2 |
Ukraine