| 1. Round | 26/02/2023 | Gualaceo SC | - | Barcelona | 2:1 |  |
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| 3. Round | 19/03/2023 | Independiente del Valle | - | Barcelona | 1:0 | ||||
| 6. Round | 16/04/2023 | LDU Quito | - | Barcelona | 0:1 | ||||
| 7. Round | 23/04/2023 | Barcelona | - | Deportivo Cuenca | 2:1 | ||||
| 9. Round | 08/05/2023 | Barcelona | - | Aucas | 5:1 | ||||
| 10. Round | 14/05/2023 | Libertad de Loja | - | Barcelona | 2:2 | ||||
| 12. Round | 29/05/2023 | El Nacional | - | Barcelona | 4:1 | ||||
| 13. Round | 04/06/2023 | Barcelona | - | Emelec | 1:3 | ||||
| 14. Round | 11/06/2023 | Guayaquil City | - | Barcelona | 1:2 | |
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| 15. Round | 19/06/2023 | Barcelona | - | Universidad Catolica | 1:2 |
Uruguay
Italy