| 1. Round | 18/10/2020 | Peña Deportiva | - | Villarreal CF B | 1:0 | ||||
| 2. Round | 24/10/2020 | Villarreal CF B | - | Levante UD B | 1:1 |  |
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| 3. Round | 01/11/2020 | CF La Nucía | - | Villarreal CF B | 1:2 | ||||
| 5. Round | 21/11/2020 | Atzeneta UE | - | Villarreal CF B | 1:1 | ||||
| 4. Round | 25/11/2020 | Villarreal CF B | - | CD Alcoyano | 3:0 | ||||
| 6. Round | 29/11/2020 | Villarreal CF B | - | Valencia CF B | 1:1 | ||||
| 8. Round | 13/12/2020 | Villarreal CF B | - | Orihuela CF | 2:0 | |
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| 13. Round | 07/02/2021 | CD Alcoyano | - | Villarreal CF B | 0:2 | ||||
| 14. Round | 14/02/2021 | Villarreal CF B | - | Atzeneta UE | 0:0 | ||||
| 15. Round | 21/02/2021 | Valencia CF B | - | Villarreal CF B | 1:1 | |
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| 17. Round | 14/03/2021 | Orihuela CF | - | Villarreal CF B | 2:4 |
Spain