| 3. Round | 03/09/2011 | Sporting Charleroi | - | KV Oostende | 2:2 | ||||
| 15. Round | 27/11/2011 | Royal Antwerp FC | - | Sporting Charleroi | 1:0 | ||||
| 16. Round | 04/12/2011 | Sporting Charleroi | - | FCV Dender EH | 1:0 | ||||
| 17. Round | 10/12/2011 | AFC Tubize | - | Sporting Charleroi | 2:1 | ||||
| 18. Round | 18/12/2011 | KVK Tienen | - | Sporting Charleroi | 0:2 | ||||
| 19. Round | 07/01/2012 | Sporting Charleroi | - | KSV Roeselare | 4:0 | ||||
| 25. Round | 19/02/2012 | Sporting Charleroi | - | RBD Borinage | 2:2 | ||||
| 28. Round | 10/03/2012 | Sporting Charleroi | - | Standaard Wetteren | 3:0 | ||||
| 29. Round | 17/03/2012 | Sporting Charleroi | - | KAS Eupen | 3:0 | ||||
| 23. Round | 25/03/2012 | Sporting Charleroi | - | R. White Star Woluwe FC | 2:0 |  |
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| 30. Round | 31/03/2012 | Lommel United | - | Sporting Charleroi | 0:2 | ||||
| 31. Round | 06/04/2012 | CS Visé | - | Sporting Charleroi | 2:2 | ||||
| 24. Round | 11/04/2012 | FC Brussels | - | Sporting Charleroi | 2:3 | ||||
| 32. Round | 16/04/2012 | Sporting Charleroi | - | Royal Antwerp FC | 0:3 | ||||
| 33. Round | 20/04/2012 | FCV Dender EH | - | Sporting Charleroi | 0:1 | |
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| 34. Round | 29/04/2012 | Sporting Charleroi | - | AFC Tubize | 1:2 |
Belgium