| 2. Round | 18/08/2024 | Heracles Almelo | - | PSV Eindhoven | 1:3 |  |
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| 3. Round | 24/08/2024 | Almere City FC | - | PSV Eindhoven | 1:7 | |
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| 4. Round | 01/09/2024 | PSV Eindhoven | - | Go Ahead Eagles | 3:0 | ||||
| 5. Round | 14/09/2024 | PSV Eindhoven | - | NEC Nijmegen | 2:0 | ||||
| 6. Round | 22/09/2024 | Fortuna Sittard | - | PSV Eindhoven | 1:3 | ||||
| 10. Round | 26/10/2024 | PSV Eindhoven | - | PEC Zwolle | 6:0 | ||||
| 11. Round | 02/11/2024 | AFC Ajax | - | PSV Eindhoven | 3:2 | ||||
| 12. Round | 09/11/2024 | NAC Breda | - | PSV Eindhoven | 0:3 | ||||
| 13. Round | 23/11/2024 | PSV Eindhoven | - | FC Groningen | 5:0 | ||||
| 21. Round | 01/02/2025 | NEC Nijmegen | - | PSV Eindhoven | 3:3 | ||||
| 24. Round | 01/03/2025 | Go Ahead Eagles | - | PSV Eindhoven | 3:2 | ||||
| 26. Round | 15/03/2025 | RKC Waalwijk | - | PSV Eindhoven | 0:3 | ||||
| 28. Round | 05/04/2025 | FC Groningen | - | PSV Eindhoven | 1:3 | ||||
| 29. Round | 12/04/2025 | PSV Eindhoven | - | Almere City FC | 5:0 | ||||
| 31. Round | 03/05/2025 | PSV Eindhoven | - | Fortuna Sittard | 4:1 |
Netherlands