| 3. Round | 05/02/2006 | Newell's Old Boys | - | River Plate | 3:1 |  |
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| 5. Round | 19/02/2006 | Colón de Santa Fe | - | River Plate | 2:2 | ||||
| 9. Round | 12/03/2006 | Independiente | - | River Plate | 1:1 | |
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| 10. Round | 19/03/2006 | River Plate | - | Olimpo de Bahía Blanca | 3:0 | ||||
| 16. Round | 23/04/2006 | River Plate | - | Argentinos Juniors | 2:2 | |
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| 18. Round | 07/05/2006 | River Plate | - | Racing Club | 0:2 |
Chile