| 18. Round | 12/01/2000 | KV Mechelen | - | Standard Liège | 2:4 | ||||
| 19. Round | 16/01/2000 | Standard Liège | - | KVC Westerlo | 4:0 |  |
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| 20. Round | 22/01/2000 | KAA Gent | - | Standard Liège | 1:5 | ||||
| 21. Round | 28/01/2000 | Standard Liège | - | KRC Genk | 5:1 | ||||
| 22. Round | 06/02/2000 | Standard Liège | - | Verbroedering Geel | 3:0 | ||||
| 23. Round | 13/02/2000 | RSC Charleroi | - | Standard Liège | 1:4 | ||||
| 24. Round | 18/02/2000 | Standard Liège | - | Excelsior Mouscron | 2:0 | ||||
| 25. Round | 04/03/2000 | KSK Beveren | - | Standard Liège | 0:2 | ||||
| 26. Round | 11/03/2000 | Standard Liège | - | Lierse SK (old) | 3:1 | ||||
| 27. Round | 19/03/2000 | Lommelse SK | - | Standard Liège | 2:1 | ||||
| 28. Round | 24/03/2000 | Standard Liège | - | Club Brugge KV | 0:1 | ||||
| 29. Round | 02/04/2000 | Sint-Truidense VV | - | Standard Liège | 2:0 | ||||
| 30. Round | 07/04/2000 | Standard Liège | - | Sporting Lokeren | 1:2 | ||||
| 31. Round | 15/04/2000 | Germinal Beerschot | - | Standard Liège | 2:0 | ||||
| 32. Round | 22/04/2000 | Standard Liège | - | K.S.C. Eendracht Aalst | 3:1 | ||||
| 33. Round | 06/05/2000 | RSC Anderlecht | - | Standard Liège | 2:0 |
Belgium