| 2. Round | 12/09/2009 | Getafe CF | - | FC Barcelona | 0:2 | ||||
| 3. Round | 19/09/2009 | FC Barcelona | - | Atlético Madrid | 5:2 |  |
|||
| 5. Round | 26/09/2009 | Málaga CF | - | FC Barcelona | 0:2 | ||||
| 8. Round | 25/10/2009 | FC Barcelona | - | Real Zaragoza | 6:1 | ||||
| 9. Round | 31/10/2009 | CA Osasuna | - | FC Barcelona | 1:1 | |
|||
| 10. Round | 07/11/2009 | FC Barcelona | - | RCD Mallorca | 4:2 | ||||
| 11. Round | 21/11/2009 | Athletic Club | - | FC Barcelona | 1:1 | ||||
| 15. Round | 02/12/2009 | Xerez CD | - | FC Barcelona | 0:2 | ||||
| 17. Round | 10/01/2010 | CD Tenerife | - | FC Barcelona | 0:5 | ||||
| 19. Round | 23/01/2010 | Real Valladolid | - | FC Barcelona | 0:3 | ||||
| 30. Round | 03/04/2010 | FC Barcelona | - | Athletic Club | 4:1 | ||||
| 34. Round | 24/04/2010 | FC Barcelona | - | Xerez CD | 3:1 |
Ukraine