| 1. Round | 14/07/2013 | Dinamo Kiev | - | Volyn Lutsk | 1:1 | ||||
| 2. Round | 21/07/2013 | Volyn Lutsk | - | Tavriya Simferopol (1958-2014) | 1:0 | ||||
| 8. Round | 01/09/2013 | Volyn Lutsk | - | Metalurh Donetsk | 1:0 |  |
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| 9. Round | 13/09/2013 | Arsenal Kiev | - | Volyn Lutsk | annull. | ||||
| 11. Round | 28/09/2013 | Zorya Lugansk | - | Volyn Lutsk | 2:0 | ||||
| 16. Round | 10/11/2013 | Volyn Lutsk | - | Dinamo Kiev | 1:4 | ||||
| 21. Round | 15/03/2014 | Karpaty Lviv | - | Volyn Lutsk | 0:1 | |
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| 22. Round | 23/03/2014 | Volyn Lutsk | - | Vorskla Poltava | 0:0 | ||||
| 25. Round | 11/04/2014 | FK Illichivets | - | Volyn Lutsk | 1:0 | ||||
| 26. Round | 20/04/2014 | Volyn Lutsk | - | Zorya Lugansk | 0:2 | ||||
| 20. Round | 24/04/2014 | Volyn Lutsk | - | Metalist Kharkiv | 1:4 | ||||
| 27. Round | 28/04/2014 | Volyn Lutsk | - | Chernomorets Odessa | 1:2 | |
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| 28. Round | 04/05/2014 | Hoverla Uzhgorod | - | Volyn Lutsk | 6:0 | ||||
| 29. Round | 11/05/2014 | Volyn Lutsk | - | PFK Sevastopol | 1:2 | ||||
| 30. Round | 18/05/2014 | Shakhtar Donetsk | - | Volyn Lutsk | 2:0 |
Ukraine