| 1. Round | 23/07/2011 | Rangers FC | - | Heart of Midlothian | 1:1 | ||||
| 2. Round | 31/07/2011 | Heart of Midlothian | - | Dundee United | 0:1 | ||||
| 3. Round | 07/08/2011 | Motherwell FC | - | Heart of Midlothian | 1:0 | ||||
| 4. Round | 13/08/2011 | Heart of Midlothian | - | Aberdeen FC | 3:0 | ||||
| 6. Round | 28/08/2011 | Heart of Midlothian | - | Hibernian FC | 2:0 | ||||
| 7. Round | 10/09/2011 | Inverness CT | - | Heart of Midlothian | 1:1 | ||||
| 10. Round | 02/10/2011 | Heart of Midlothian | - | Celtic FC | 2:0 | ||||
| 11. Round | 15/10/2011 | Dunfermline Athletic | - | Heart of Midlothian | 0:2 | ||||
| 12. Round | 23/10/2011 | Heart of Midlothian | - | Rangers FC | 0:2 | ||||
| 13. Round | 29/10/2011 | Heart of Midlothian | - | Kilmarnock FC | 0:1 | ||||
| 14. Round | 05/11/2011 | St. Mirren FC | - | Heart of Midlothian | 0:0 | ||||
| 15. Round | 19/11/2011 | Dundee United | - | Heart of Midlothian | 1:0 | ||||
| 16. Round | 26/11/2011 | Heart of Midlothian | - | Inverness CT | 2:1 |  |
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| 17. Round | 03/12/2011 | Heart of Midlothian | - | St. Johnstone FC | 1:2 | ||||
| 18. Round | 10/12/2011 | Celtic FC | - | Heart of Midlothian | 1:0 |
Iceland