| Group 2 | 11/02/2014 | Botafogo - RJ | - | San Lorenzo | 2:0 |  |
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| Group 2 | 27/02/2014 | San Lorenzo | - | Club Social y Deportivo Independiente José Terán | 1:0 | ||||
| Group 2 | 12/03/2014 | San Lorenzo | - | Unión Española | 1:1 | ||||
| Group 2 | 21/03/2014 | Unión Española | - | San Lorenzo | 1:0 | ||||
| Group 2 | 27/03/2014 | Club Social y Deportivo Independiente José Terán | - | San Lorenzo | 1:1 | |
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| Group 2 | 10/04/2014 | San Lorenzo | - | Botafogo - RJ | 3:0 | ||||
| Round of 16 | 24/04/2014 | San Lorenzo | - | Grêmio Porto Alegre | 1:0 | |
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| Round of 16 | 01/05/2014 | Grêmio Porto Alegre | - | San Lorenzo | 2:4 pso | ||||
| Quarter-finals | 08/05/2014 | San Lorenzo | - | Cruzeiro | 1:0 | ||||
| Quarter-finals | 15/05/2014 | Cruzeiro | - | San Lorenzo | 1:1 | ||||
| Semi-finals | 23/07/2014 | San Lorenzo | - | Bolívar | 5:0 |  |
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| Semi-finals | 31/07/2014 | Bolívar | - | San Lorenzo | 1:0 | ||||
| Final | 07/08/2014 | Club Nacional | - | San Lorenzo | 1:1 | ||||
| Final | 14/08/2014 | San Lorenzo | - | Club Nacional | 1:0 |
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