| 2. Round | 23/08/2013 | Athletic Club | - | CA Osasuna | 2:0 | ||||
| 8. Round | 06/10/2013 | Athletic Club | - | Valencia CF | 1:1 |  |
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| 20. Round | 20/01/2014 | Athletic Club | - | Real Valladolid | 4:2 | ||||
| 25. Round | 23/02/2014 | Real Betis | - | Athletic Club | 0:2 | ||||
| 26. Round | 28/02/2014 | Athletic Club | - | Granada CF | 4:0 |
Spain