| 1. Round | 13/02/2005 | Colón de Santa Fe | - | River Plate | 2:3 |  |
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| 3. Round | 27/02/2005 | Argentinos Juniors | - | River Plate | 3:3 | ||||
| 5. Round | 13/03/2005 | River Plate | - | Racing Club | 1:0 |  |
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| 7. Round | 03/04/2005 | River Plate | - | Arsenal de Sarandí | 2:0 | |
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| 8. Round | 10/04/2005 | Newell's Old Boys | - | River Plate | 4:2 | ||||
| 10. Round | 24/04/2005 | Almagro | - | River Plate | 2:5 | |
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| 12. Round | 08/05/2005 | San Lorenzo | - | River Plate | 3:1 | ||||
| 14. Round | 22/05/2005 | Boca Juniors | - | River Plate | 2:1 | ||||
| 19. Round | 03/07/2005 | River Plate | - | Huracán de Tres Arroyos | 1:0 |
Argentina