| 1. Round | 23/01/2013 | Club León | - | Deportes Iquique | 1:1 | ||||
| 1. Round | 30/01/2013 | Deportes Iquique | - | Club León | 4:2 pso | ||||
| Group 4 | 13/02/2013 | Deportes Iquique | - | Peñarol | 1:2 | ||||
| Group 4 | 20/02/2013 | Vélez Sarsfield | - | Deportes Iquique | 3:0 |  |
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| Group 4 | 27/02/2013 | Deportes Iquique | - | Emelec | 2:0 | ||||
| Group 4 | 06/03/2013 | Emelec | - | Deportes Iquique | 2:1 | ||||
| Group 4 | 02/04/2013 | Deportes Iquique | - | Vélez Sarsfield | 1:3 | ||||
| Group 4 | 09/04/2013 | Peñarol | - | Deportes Iquique | 3:0 | |
Chile