| 1. Round | 18/08/2013 | Apollon Smyrnis | - | Aris Saloniki | 2:1 | ||||
| 2. Round | 25/08/2013 | PAS Giannina | - | Apollon Smyrnis | 2:0 | ||||
| 6. Round | 29/09/2013 | Apollon Smyrnis | - | Levadiakos | 4:2 | ||||
| 7. Round | 06/10/2013 | Skoda Xanthi | - | Apollon Smyrnis | 3:2 | ||||
| 8. Round | 20/10/2013 | Apollon Smyrnis | - | Panetolikos | 1:1 | ||||
| 9. Round | 27/10/2013 | Panionios GSS | - | Apollon Smyrnis | 2:1 | ||||
| 14. Round | 08/12/2013 | PAOK Saloniki | - | Apollon Smyrnis | 0:0 |  |
|||
| 15. Round | 15/12/2013 | Apollon Smyrnis | - | Panthrakikos | 3:2 | ||||
| 16. Round | 18/12/2013 | Ergotelis | - | Apollon Smyrnis | 2:2 | ||||
| 17. Round | 21/12/2013 | Apollon Smyrnis | - | Olympiakos Piraeus | 0:5 | |
|||
| 18. Round | 06/01/2014 | Aris Saloniki | - | Apollon Smyrnis | 0:2 | |
|||
| 23. Round | 05/02/2014 | Levadiakos | - | Apollon Smyrnis | 1:1 | ||||
| 27. Round | 01/03/2014 | Veria FC | - | Apollon Smyrnis | 1:1 | |
|||
| 32. Round | 30/03/2014 | Panthrakikos | - | Apollon Smyrnis | 2:3 | ||||
| 33. Round | 06/04/2014 | Apollon Smyrnis | - | Ergotelis | 1:0 | |
|||
| 34. Round | 13/04/2014 | Olympiakos Piraeus | - | Apollon Smyrnis | 1:0 | |
Greece