| 1. Round | 16/08/1969 | FC Schalke 04 | - | Bor. Mönchengladbach | 2:0 | ||||
| 2. Round | 22/08/1969 | Eintracht Frankfurt | - | FC Schalke 04 | 2:1 | ||||
| 3. Round | 30/08/1969 | FC Schalke 04 | - | 1. FC Kaiserslautern | 4:2 |  |
|||
| 4. Round | 06/09/1969 | Borussia Dortmund | - | FC Schalke 04 | 1:1 | |
|||
| 5. Round | 13/09/1969 | FC Schalke 04 | - | Eintracht Braunschweig | 1:1 | ||||
| 7. Round | 04/10/1969 | FC Schalke 04 | - | MSV Duisburg | 0:0 | ||||
| 13. Round | 15/11/1969 | FC Schalke 04 | - | Hannover 96 | 2:0 | ||||
| 14. Round | 29/11/1969 | Hamburger SV | - | FC Schalke 04 | 1:1 | ||||
| 17. Round | 25/02/1970 | Bayern München | - | FC Schalke 04 | 6:0 | ||||
| 25. Round | 28/02/1970 | FC Schalke 04 | - | TSV 1860 München | 3:1 | |
|||
| 26. Round | 07/03/1970 | Alemannia Aachen | - | FC Schalke 04 | 1:2 | ||||
| 18. Round | 11/03/1970 | Bor. Mönchengladbach | - | FC Schalke 04 | 2:0 | ||||
| 27. Round | 14/03/1970 | FC Schalke 04 | - | Hertha BSC | 1:3 | ||||
| 28. Round | 21/03/1970 | VfB Stuttgart | - | FC Schalke 04 | 2:0 | ||||
| 23. Round | 25/03/1970 | FC Schalke 04 | - | Werder Bremen | 0:0 | ||||
| 29. Round | 28/03/1970 | FC Schalke 04 | - | 1. FC Köln | 1:0 | ||||
| 30. Round | 04/04/1970 | Hannover 96 | - | FC Schalke 04 | 3:1 | |
Austria