| 6. Round | 11/09/2010 | Germinal Beerschot | - | Sporting Charleroi | 1:0 |  |
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| 7. Round | 19/09/2010 | Sporting Charleroi | - | Club Brugge KV | 0:5 | ||||
| 10. Round | 02/10/2010 | SV Zulte Waregem | - | Sporting Charleroi | 1:1 | ||||
| 11. Round | 16/10/2010 | Sporting Charleroi | - | Sporting Lokeren | 1:2 |  |
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| 12. Round | 23/10/2010 | Sint-Truidense VV | - | Sporting Charleroi | 3:2 | |
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| 13. Round | 29/10/2010 | Sporting Charleroi | - | KV Kortrijk | 0:0 | ||||
| 14. Round | 06/11/2010 | KV Mechelen | - | Sporting Charleroi | 2:0 | ||||
| 15. Round | 13/11/2010 | Sporting Charleroi | - | KVC Westerlo | 0:1 | ||||
| 20. Round | 18/12/2010 | KAS Eupen | - | Sporting Charleroi | 1:0 | ||||
| 22. Round | 29/12/2010 | Club Brugge KV | - | Sporting Charleroi | 5:0 | ||||
| 23. Round | 22/01/2011 | Sporting Charleroi | - | KV Mechelen | 0:0 |
Finland