| Group 2 | 27/02/1966 | Club Olimpia | - | Guaraní | 3:3 | ||||
| Group 2 | 05/03/1966 | Universidad de Chile | - | Club Olimpia | 1:2 | ||||
| Group 2 | 08/03/1966 | Universidad Católica | - | Club Olimpia | 0:0 | ||||
| Group 2 | 11/03/1966 | Club Olimpia | - | Universidad Católica | 0:4 |
| Group 2 | 27/02/1966 | Club Olimpia | - | Guaraní | 3:3 | ||||
| Group 2 | 05/03/1966 | Universidad de Chile | - | Club Olimpia | 1:2 | ||||
| Group 2 | 08/03/1966 | Universidad Católica | - | Club Olimpia | 0:0 | ||||
| Group 2 | 11/03/1966 | Club Olimpia | - | Universidad Católica | 0:4 |
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