| 1. Round | 01/09/1990 | Real Madrid | - | CD Castellón | 1:0 | ||||
| 2. Round | 07/09/1990 | Sevilla FC | - | Real Madrid | 2:0 |  |
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| 3. Round | 14/09/1990 | Real Madrid | - | RCD Mallorca | 3:0 |  |
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| 4. Round | 21/09/1990 | Real Zaragoza | - | Real Madrid | 1:3 | |
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| 5. Round | 29/09/1990 | Real Madrid | - | Cádiz CF | 2:1 | |
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| 6. Round | 07/10/1990 | Real Sociedad | - | Real Madrid | 1:1 | |
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| 7. Round | 14/10/1990 | Real Madrid | - | CD Logroñés | 0:0 | ||||
| 8. Round | 21/10/1990 | Real Oviedo | - | Real Madrid | 0:0 | ||||
| 9. Round | 28/10/1990 | Real Burgos | - | Real Madrid | 2:1 | |
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| 10. Round | 03/11/1990 | Real Madrid | - | Espanyol Barcelona | 2:1 | ||||
| 11. Round | 16/11/1990 | Valencia CF | - | Real Madrid | 2:1 | |
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| 13. Round | 30/11/1990 | Real Valladolid | - | Real Madrid | 0:1 | |
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| 14. Round | 08/12/1990 | Real Madrid | - | CD Tenerife | 3:0 | |
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| 15. Round | 14/12/1990 | Athletic Club | - | Real Madrid | 1:0 | ||||
| 18. Round | 11/01/1991 | Real Madrid | - | Atlético Madrid | 0:3 | |
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| 19. Round | 18/01/1991 | FC Barcelona | - | Real Madrid | 2:1 | ||||
| 20. Round | 26/01/1991 | CD Castellón | - | Real Madrid | 0:3 | |
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| 22. Round | 09/02/1991 | RCD Mallorca | - | Real Madrid | 1:1 | |
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| 27. Round | 23/03/1991 | Real Madrid | - | Real Oviedo | 1:1 | |
Mexico