| 1. Round | 29/07/2012 | Standard Liège | - | SV Zulte Waregem | 0:1 | ||||
| 2. Round | 03/08/2012 | Lierse SK (old) | - | Standard Liège | 0:0 | ||||
| 3. Round | 10/08/2012 | Standard Liège | - | Waasland-Beveren | 3:1 |  |
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| 5. Round | 26/08/2012 | Standard Liège | - | KV Mechelen | 3:2 | |
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| 6. Round | 02/09/2012 | Club Brugge KV | - | Standard Liège | 4:2 | |
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| 7. Round | 16/09/2012 | Beerschot AC | - | Standard Liège | 3:2 | |
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| 8. Round | 21/09/2012 | Standard Liège | - | KAA Gent | 1:2 |  |
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| 9. Round | 30/09/2012 | KV Kortrijk | - | Standard Liège | 2:1 | |
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| 10. Round | 07/10/2012 | Standard Liège | - | RSC Anderlecht | 2:1 | |
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| 12. Round | 26/10/2012 | Standard Liège | - | Cercle Brugge | 2:1 | |
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| 19. Round | 07/12/2012 | Standard Liège | - | Sporting Charleroi | 6:1 | ||||
| 22. Round | 27/12/2012 | Standard Liège | - | Beerschot AC | 3:0 |
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