| 1. Round | 06/08/2022 | PSV Eindhoven | - | FC Emmen | 4:1 | ||||
| 2. Round | 13/08/2022 | Go Ahead Eagles | - | PSV Eindhoven | 2:5 | ||||
| 4. Round | 28/08/2022 | SBV Excelsior | - | PSV Eindhoven | 1:6 | ||||
| 6. Round | 11/09/2022 | PSV Eindhoven | - | RKC Waalwijk | 1:0 | ||||
| 7. Round | 18/09/2022 | PSV Eindhoven | - | Feyenoord | 4:3 | ||||
| 8. Round | 01/10/2022 | SC Cambuur | - | PSV Eindhoven | 3:0 | ||||
| 9. Round | 09/10/2022 | sc Heerenveen | - | PSV Eindhoven | 0:1 | ||||
| 16. Round | 15/01/2023 | Fortuna Sittard | - | PSV Eindhoven | 2:2 | ||||
| 19. Round | 28/01/2023 | PSV Eindhoven | - | Go Ahead Eagles | 2:0 | ||||
| 21. Round | 11/02/2023 | PSV Eindhoven | - | FC Groningen | 6:0 | ||||
| 22. Round | 19/02/2023 | FC Utrecht | - | PSV Eindhoven | 2:2 | ||||
| 23. Round | 26/02/2023 | PSV Eindhoven | - | FC Twente | 3:1 | ||||
| 24. Round | 05/03/2023 | RKC Waalwijk | - | PSV Eindhoven | 0:1 | ||||
| 25. Round | 12/03/2023 | PSV Eindhoven | - | SC Cambuur | 5:2 | ||||
| 27. Round | 01/04/2023 | NEC Nijmegen | - | PSV Eindhoven | 2:4 | ||||
| 29. Round | 16/04/2023 | FC Volendam | - | PSV Eindhoven | 2:3 | ||||
| 30. Round | 23/04/2023 | PSV Eindhoven | - | AFC Ajax | 3:0 |
Spain
Belgium 