| 2. Round | 31/07/2022 | KRC Genk | - | Standard Liège | 3:1 | ||||
| 3. Round | 07/08/2022 | Standard Liège | - | Cercle Brugge | 2:0 | ||||
| 4. Round | 13/08/2022 | KVC Westerlo | - | Standard Liège | 4:2 | ||||
| 5. Round | 21/08/2022 | Standard Liège | - | Oud-Heverlee Leuven | 1:3 |  |
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| 8. Round | 09/09/2022 | Sint-Truidense VV | - | Standard Liège | 1:2 | ||||
| 9. Round | 18/09/2022 | Standard Liège | - | Club Brugge KV | 3:0 | ||||
| 10. Round | 30/09/2022 | Standard Liège | - | RFC Seraing | 0:2 | ||||
| 11. Round | 09/10/2022 | Sporting Charleroi | - | Standard Liège | 0:1 |  |
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| 12. Round | 16/10/2022 | Standard Liège | - | Royal Antwerp FC | 3:0 | ||||
| 13. Round | 19/10/2022 | KV Mechelen | - | Standard Liège | 2:0 | ||||
| 15. Round | 29/10/2022 | SV Zulte Waregem | - | Standard Liège | 0:3 | ||||
| 18. Round | 23/12/2022 | KAA Gent | - | Standard Liège | 0:0 | |
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| 19. Round | 06/01/2023 | Standard Liège | - | Sint-Truidense VV | 1:1 | ||||
| 20. Round | 14/01/2023 | RFC Seraing | - | Standard Liège | 1:1 | ||||
| 21. Round | 17/01/2023 | Standard Liège | - | KV Mechelen | 2:0 | ||||
| 34. Round | 23/04/2023 | Oud-Heverlee Leuven | - | Standard Liège | 3:2 |
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