| 1. Round | 17/04/2021 | Gaz Metan Mediaş | - | FC Voluntari | 1:1 | ||||
| 2. Round | 22/04/2021 | FC Politehnica Iași | - | FC Voluntari | 0:1 | ||||
| 3. Round | 26/04/2021 | FC Voluntari | - | FC Viitorul Constanța | 1:0 |  |
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| 4. Round | 29/04/2021 | Dinamo Bucureşti | - | FC Voluntari | 2:0 | ||||
| 5. Round | 02/05/2021 | FC Voluntari | - | FC Hermannstadt | 0:1 | ||||
| 6. Round | 06/05/2021 | Argeș Pitești | - | FC Voluntari | 3:0 | ||||
| 7. Round | 10/05/2021 | FC Voluntari | - | Chindia Târgoviște | 0:0 | ||||
| 8. Round | 15/05/2021 | Astra Giurgiu | - | FC Voluntari | 0:3 | |
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| 9. Round | 19/05/2021 | FC Voluntari | - | UTA Arad | 0:0 |
Spain