| 3. Round | 26/02/2023 | Deportes Iquique | - | San Luis | 3:2 | ||||
| 4. Round | 06/03/2023 | San Luis | - | Deportes Temuco | 1:0 | ||||
| 14. Round | 28/05/2023 | San Luis | - | Cobreloa | 2:1 | ||||
| 15. Round | 04/06/2023 | Universidad de Concepción | - | San Luis | 0:2 | ||||
| 16. Round | 19/06/2023 | San Luis | - | Unión San Felipe | 1:2 | ||||
| 19. Round | 22/07/2023 | Deportes Temuco | - | San Luis | 1:2 | ||||
| 17. Round | 02/08/2023 | Santiago Morning | - | San Luis | 1:0 | ||||
| 22. Round | 13/08/2023 | Antofagasta | - | San Luis | 1:0 |  |
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| 23. Round | 20/08/2023 | San Luis | - | Puerto Montt | 0:0 | ||||
| 26. Round | 09/09/2023 | San Luis | - | Rangers | 0:0 | ||||
| 29. Round | 09/10/2023 | Cobreloa | - | San Luis | 1:0 | ||||
| 30. Round | 15/10/2023 | San Luis | - | Universidad de Concepción | 2:3 |
Chile