| 1. Round | 19/01/2014 | Blooming | - | Club San José | 2:1 | ||||
| 2. Round | 26/01/2014 | Club San José | - | Real Potosí | 1:1 | ||||
| 3. Round | 02/02/2014 | Sport Boys Warnes | - | Club San José | 1:0 | ||||
| 5. Round | 16/02/2014 | Bolívar | - | Club San José | 0:1 |  |
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| 7. Round | 23/02/2014 | Nacional Potosí | - | Club San José | 1:4 | ||||
| 8. Round | 09/03/2014 | Jorge Wilstermann | - | Club San José | 0:0 | |
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| 9. Round | 13/03/2014 | Club San José | - | Universitario de Sucre | 4:3 | ||||
| 10. Round | 15/03/2014 | The Strongest | - | Club San José | 3:1 | |
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| 11. Round | 23/03/2014 | CD Guabirá | - | Club San José | 3:4 | ||||
| 12. Round | 29/03/2014 | Club San José | - | Blooming | 3:1 | ||||
| 13. Round | 06/04/2014 | Real Potosí | - | Club San José | 1:2 | |
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| 19. Round | 11/05/2014 | Club San José | - | Jorge Wilstermann | 0:1 |
Bolivia