| 1. Round | 11/08/2012 | Roda JC Kerkrade | - | PEC Zwolle | 1:1 | ||||
| 2. Round | 18/08/2012 | PEC Zwolle | - | Vitesse | 0:1 | ||||
| 3. Round | 25/08/2012 | FC Utrecht | - | PEC Zwolle | 1:1 | ||||
| 4. Round | 01/09/2012 | PEC Zwolle | - | NEC Nijmegen | 0:4 |  |
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| 6. Round | 22/09/2012 | PEC Zwolle | - | FC Groningen | 1:2 | ||||
| 9. Round | 21/10/2012 | RKC Waalwijk | - | PEC Zwolle | 1:2 |  |
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| 10. Round | 28/10/2012 | PEC Zwolle | - | PSV Eindhoven | 1:2 |  |
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| 11. Round | 04/11/2012 | sc Heerenveen | - | PEC Zwolle | 2:1 | |
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| 12. Round | 11/11/2012 | PEC Zwolle | - | AFC Ajax | 2:4 | ||||
| 13. Round | 17/11/2012 | PEC Zwolle | - | NAC Breda | 2:0 | ||||
| 14. Round | 25/11/2012 | FC Twente | - | PEC Zwolle | 2:2 | |
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| 16. Round | 08/12/2012 | ADO Den Haag | - | PEC Zwolle | 1:1 | ||||
| 17. Round | 15/12/2012 | PEC Zwolle | - | AZ Alkmaar | 1:2 |  |
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| 18. Round | 22/12/2012 | Heracles Almelo | - | PEC Zwolle | 1:1 | ||||
| 19. Round | 18/01/2013 | PSV Eindhoven | - | PEC Zwolle | 1:3 | ||||
| 20. Round | 26/01/2013 | PEC Zwolle | - | sc Heerenveen | 1:1 | |
Netherlands