| 1. Round | 26/07/2013 | Club Rubio Ñu | - | Club Nacional | 2:2 | ||||
| 2. Round | 03/08/2013 | Club Nacional | - | Sol de América | 1:2 | ||||
| 3. Round | 11/08/2013 | General Díaz | - | Club Nacional | 0:0 | ||||
| 4. Round | 18/08/2013 | Club Nacional | - | Club Olimpia | 1:1 | ||||
| 6. Round | 26/08/2013 | Club Nacional | - | Sportivo Carapeguá | 5:2 | ||||
| 5. Round | 08/09/2013 | Sportivo Luqueño | - | Club Nacional | 2:2 | ||||
| 10. Round | 22/09/2013 | Guaraní | - | Club Nacional | 0:1 |  |
|||
| 11. Round | 28/09/2013 | Club Nacional | - | Cerro Porteño | 0:1 | ||||
| 12. Round | 05/10/2013 | Club Nacional | - | Club Rubio Ñu | 0:1 | ||||
| 7. Round | 12/10/2013 | Libertad | - | Club Nacional | 2:0 |  |
|||
| 15. Round | 26/10/2013 | Club Olimpia | - | Club Nacional | 0:1 | |
|||
| 17. Round | 09/11/2013 | Sportivo Carapeguá | - | Club Nacional | 1:4 | ||||
| 18. Round | 13/11/2013 | Club Nacional | - | Libertad | 0:1 | ||||
| 20. Round | 23/11/2013 | Club Nacional | - | Cerro de Franco | 1:0 | |
|||
| 22. Round | 06/12/2013 | Cerro Porteño | - | Club Nacional | 4:1 | |
Paraguay